Once you have set the methods and shipping zones, you can start to create the actual shipping rates. Click the 'Shipping Methods tab' and then click the 'Rates' link by the first shipping method.

This brings up a list of the bands that are in effect for each shipping zone. You can create any number of bands for each zone to fine tune the shipping price for any weight/value. This process can be repeated for each shipping method.

If a real-time shipping price system like UPS, USPS or Fedex is enabled, you can also specify that this be used for that particular band.